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Author(s):   Timonen, R.
Title:   Kinetics of the reactions of some polyatomic free radicals with Cl2 and Br2, and reactions of formyl radicals with O2, NO2, Cl2, Br2, and H atoms
Journal:   Ann. Acad. Sci. Fenn. Ser. A2
Volume:   218
Page(s):   5 - 45
Year:   1988
Reference type:   Journal article
Squib:   1988TIM5-45

Reaction:   ·CClF2 + Cl2CF2Cl2 + ·Cl
Reaction order:   2
Temperature:   376 - 626 K
Pressure:  7.33E-4 - 3.31E-3 bar
Rate expression:   1.29x10-12 [cm3/molecule s] e-7999 [±3043 J/mole]/RT
Uncertainty:   1.7400000095367432
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
376 9.98E-14
400 1.16E-13
425 1.34E-13
450 1.52E-13
475 1.70E-13
500 1.88E-13
525 2.06E-13
550 2.24E-13
575 2.42E-13
600 2.59E-13
625 2.76E-13
626 2.77E-13