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Accessibility information
Author(s):   Harris, G.W.; Pitts, J.N., Jr.
Title:   Absolute Rate Constants and Temperature Dependences for the Gas Phase Reactions of H Atoms with Propene and the Butenes in the Temperature Range 298 to 445 K
Journal:   J. Chem. Phys.
Volume:   77
Year:   1982
Reference type:   Journal article
Squib:   1982HAR/PIT3994

Reaction:   (E)-2-C4H8 + sec-C4H9
Reaction order:   2
Temperature:   298 - 445 K
Pressure:  6.67E-2 bar
Rate expression:   3.45x10-11 [±3.49x10-12 cm3/molecule s] e-8647 [±520 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.05E-12
300 1.08E-12
325 1.41E-12
350 1.77E-12
375 2.16E-12
400 2.57E-12
425 2.99E-12
445 3.34E-12