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Accessibility information
Author(s):   Kyogoku, T.; Watanabe, T.; Tsunashima, S.; Sato, S.
Title:   Arrhenius parameters for the reactions of hydrogen and deuterium atoms with four butenes
Journal:   Bull. Chem. Soc. Jpn.
Volume:   56
Page(s):   19 - 21
Year:   1983
Reference type:   Journal article
Squib:   1983KYO/WAT19-21

Reaction:   (E)-2-C4H8 + sec-C4H9
Reaction order:   2
Temperature:   200 - 500 K
Pressure:  0.80 bar
Rate expression:   3.97x10-11 [±2.82x10-12 cm3/molecule s] e-8813 [±175 J/mole]/RT
Bath gas:   H2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Chemical activation
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
200 1.98E-13
225 3.57E-13
250 5.72E-13
275 8.41E-13
300 1.16E-12
325 1.52E-12
350 1.92E-12
375 2.35E-12
400 2.80E-12
425 3.28E-12
450 3.76E-12
475 4.26E-12
500 4.76E-12