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Accessibility information
Author(s):   Balaganesh, M.; Dash, M. R.; Rajakumar, B.
Title:   Experimental and Computational Investigation on the Gas Phase Reaction of Ethyl Formate with Cl Atoms
Journal:   J. Phys. Chem. A
Volume:   118
Page(s):   5272 - 5278
Year:   2014
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2014BAL/DAS5272-5278

Reaction:   HC(O)OC2H5 + ·Cl → Products
Reaction order:   2
Reference reaction:   C2H5Cl + ·Cl → Products
Temperature:   268 - 343 K
Pressure:  0.93 bar
Rate expression:   3.54x10-13 [±7.95x10-14 cm3/molecule s] (T/298 K)4.10 e-8156 [±848 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Error limits are 2 σ.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
268 5.89E-15
275 7.19E-15
300 1.38E-14
325 2.47E-14
343 3.61E-14