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Accessibility information
Author(s):   Greiner, N.R.
Title:   Hydroxyl radical kinetics by kinetic spectroscopy. VI. Reactions with alkanes in the range 300-500°K
Journal:   J. Chem. Phys.
Volume:   53
Year:   1970
Reference type:   Journal article
Squib:   1970GRE1070

Reaction:   C3H8 + ·OH1-C3H7 + H2O
Reaction order:   2
Temperature:   299 - 497 K
Pressure:  0.13 bar
Rate expression:   6.13x10-12 [cm3/molecule s] e-6843 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
299 3.91E-13
300 3.94E-13
325 4.87E-13
350 5.84E-13
375 6.83E-13
400 7.83E-13
425 8.84E-13
450 9.84E-13
475 1.08E-12
497 1.17E-12