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Accessibility information
Author(s):   Garrett, B.C.; Truhlar, D.G.
Title:   Generalized transition state theory. Canonical variational calculations using the bond energy-bond order method for bimolecular reactions of combustion products
Journal:   J. Am. Chem. Soc.
Volume:   101
Year:   1979
Reference type:   Journal article
Squib:   1979GAR/TRU5207

Reaction:   HF + ·ClClF +
Reaction order:   2
Temperature:   300 - 1000 K
Rate expression:   2.51x10-10 [cm3/molecule s] e-331747 [J/mole]/RT
Category:  Theory
Data type:   Bond energy-bond order (BEBO)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 4.35E-68
350 7.76E-60
400 1.20E-53
450 7.79E-49
500 5.53E-45
550 7.82E-42
600 3.30E-39
650 5.50E-37
700 4.41E-35
750 1.97E-33
800 5.48E-32
850 1.03E-30
900 1.40E-29
950 1.44E-28
1000 1.18E-27