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 Author(s):   Dean, A.M.
Title:   Predictions of pressure and temperature effects upon radical addition and recombination reactions
Journal:   J. Phys. Chem.
Volume:   89
Page(s):   4600 - 4608
Year:   1985
Reference type:   Journal article
Squib:   1985DEA4600-4608

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1985DEA4600-4608   CH4 → ·CH3 + H·  300 - 2500   1.00E16       4.39E05      1
  1985DEA4600-4608   C2H6 → ·CH3 + ·CH3  300 - 2500   7.94E16       3.74E05      1
  1985DEA4600-4608   C2H6 → ·C2H5 + H·  300 - 2500   1.26E16       4.10E05      1
  1985DEA4600-4608   C2H4 → C2H3 + H·  300 - 2500   2.00E16       4.61E05      1
  1985DEA4600-4608   C3H8 → 2-C3H7 + H·  300 - 2500   6.31E15       3.97E05      1
  1985DEA4600-4608   C3H8 → 1-C3H7 + H·  300 - 2500   1.58E16       4.08E05      1
  1985DEA4600-4608   C3H8 → ·C2H5 + ·CH3  300 - 2500   7.94E16       3.58E05      1
  1985DEA4600-4608   1-C4H10 → 1-C3H7 + ·CH3  300 - 2500   1.00E17       3.54E05      1
  1985DEA4600-4608   1-C4H10 → sec-C4H9 + H·  300 - 2500   1.00E16       3.97E05      1
  1985DEA4600-4608   1-C4H10 → 1-C4H9 + H·  300 - 2500   1.58E16       4.10E05      1
  1985DEA4600-4608   1-C4H10 → ·C2H5 + ·C2H5  300 - 2500   7.94E16       3.36E05      1
  1985DEA4600-4608   1-C4H8 → ·CH2CH=CH2 + ·CH3  300 - 2500   1.00E16       3.05E05      1
  1985DEA4600-4608   1-C4H8 → H· + CH2=CHCH(·)CH3  300 - 2500   1.26E15       3.45E05      1
  1985DEA4600-4608   1,3-Butadiene → H· + CH2=CHCH=CH·  300 - 2500   1.58E16       4.61E05      1
  1985DEA4600-4608   1-butyne → ·CH3 + ·CH2C≡CH  300 - 2500   5.01E15       3.17E05      1
  1985DEA4600-4608   CH3CH=CHCH3 → ·CH3 + CH3CH=C(·)H  300 - 2500   3.16E17       4.16E05      1
  1985DEA4600-4608   CH3CH=CHCH3 → H· + ·CH2CH=CHCH3  300 - 2500   3.98E15       3.56E05      1
  1985DEA4600-4608   Cyclohexene → 2-Cyclohexenyl + H·  300 - 2500   5.01E15       3.42E05      1
  1985DEA4600-4608   CH3CH=CH2 → ·CH3 + C2H3  300 - 2500   7.94E16       4.17E05      1
  1985DEA4600-4608   2-butyne → H· + CH3C≡CCH2·  300 - 2500   3.16E15       3.65E05      1
  1985DEA4600-4608   1,2-butadiene → H· + 2,3-Butanediyl  300 - 2500   2.00E15       3.59E05      1
  1985DEA4600-4608   1,5-Hexadiene → Other Products + H·  300 - 2500   2.51E15       3.45E05      1
  1985DEA4600-4608   1,5-Hexadiene → ·CH2CH=CH2 + ·CH2CH=CH2  300 - 2500   2.00E15       2.38E05      1
  1985DEA4600-4608   1,3-Cyclohexadiene → H· + 2,4-Cyclohexadien-1-yl  300 - 2500   5.01E15       3.03E05      1
  1985DEA4600-4608   HC≡CCH2CH2C≡CH → ·CH2C≡CH + ·CH2C≡CH  300 - 2500   6.31E14       2.59E05      1
  1985DEA4600-4608   HC≡CCH2CH2C≡CH → H· + 3-Butynyl, 1-(ethynyl)-  300 - 2500   2.00E15       3.46E05      1
  1985DEA4600-4608   ·CH2CH=CH2 → CH2=C=CH2 + H·  300 - 2500   1.26E13       2.56E05      1
  1985DEA4600-4608   2-C3H7 → CH3CH=CH2 + H·  300 - 2500   3.98E13       1.65E05      1
  1985DEA4600-4608   1-C3H7 → C2H4 + ·CH3  300 - 2500   1.00E13       1.38E05      1
  1985DEA4600-4608   1-C3H7 → CH3CH=CH2 + H·  300 - 2500   1.26E13       1.61E05      1
  1985DEA4600-4608   sec-C4H9 → 1-C4H8 + H·  300 - 2500   1.58E13       1.65E05      1
  1985DEA4600-4608   sec-C4H9 → CH3CH=CHCH3 + H·  300 - 2500   3.16E12       1.55E05      1
  1985DEA4600-4608   sec-C4H9 → CH3CH=CH2 + ·CH3  300 - 2500   6.31E12       1.36E05      1
  1985DEA4600-4608   1-C4H9 → C2H4 + ·C2H5  300 - 2500   5.01E12       1.16E05      1
  1985DEA4600-4608   1-C4H9 → 1-C4H8 + H·  300 - 2500   1.00E14       1.60E05      1
  1985DEA4600-4608   C2H3 → C2H2 + H·  300 - 2500   3.16E12       1.60E05      1
  1985DEA4600-4608   CH3CH=C(·)H → C2H2 + ·CH3  300 - 2500   1.26E13       1.40E05      1
  1985DEA4600-4608   CH3CH=C(·)H → CH3CCH + H·  300 - 2500   3.98E12       1.53E05      1
  1985DEA4600-4608   1-Hexen-5-yne → ·CH2CH=CH2 + ·CH2C≡CH  300 - 2500   1.26E15       2.49E05      1
  1985DEA4600-4608   ·C2H5 → C2H4 + H·  300 - 2500   5.01E13       1.71E05      1
  1985DEA4600-4608   2,4-Cyclohexadien-1-yl → Benzene + H·  300 - 2500   3.16E13       1.19E05      1
  1985DEA4600-4608   CH3CH=C(·)CH3 → CH3CCH + ·CH3  300 - 2500   5.01E13       1.31E05      1
  1985DEA4600-4608   CH2=CHCH=CH· → C2H2 + C2H3  300 - 2500   1.00E14       1.84E05      1
  1985DEA4600-4608   CH2=CHCH=CHCH=CH· → C2H2 + CH2=CHCH=CH·  300 - 2500   3.16E13       1.80E05      1
Search returned 44 records.