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Accessibility information
Author(s):   Davison, I.M.T.; Eaborn, C.; Lilly, M.N.
Title:   Gas-phase reactions of halogenoalkylsilanes. Part I. 2-chloroethyltrichlorosilane
Journal:   J. Am. Chem. Soc.
Page(s):   2624 - 2630
Year:   1964
Reference type:   Journal article
Squib:   1964DAV/EAB2624-2630

Reaction:   ClCH2CH2SiCl3 → C2H4 + SiCl4
Reaction order:   1
Temperature:   629 - 690 K
Pressure:  1.63E-2 - 0.18 bar
Rate expression:   1.82x1011 [s-1] e-190401 [±8314472 J/mole]/RT
Uncertainty:   1.45000005
Bath gas:   ClCH2CH2SiCl3
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
629 2.81E-5
650 9.11E-5
675 3.36E-4
690 7.02E-4