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Author(s):   Eaborn, C.; Mahmoud, F.M.S.; Taylor, R.
Title:   The mechanism of the gas-phase pyrolysis of esters. Part 13. The very strong activating effects of β-trialkylmetal groups
Journal:   J. Chem. Soc. Perkin Trans. 2
Page(s):   1313 - 1319
Year:   1982
Reference type:   Journal article
Squib:   1982EAB/MAH1313-1319

Reaction:   Ethanol, 2-(dimethylphenylsilyl)-, acetate → CH3C(O)OH + Silane, ethenyldimethylphenyl-
Reaction order:   1
Temperature:   593 - 670 K
Rate expression:   1.55x1012 [s-1] e-174604 [J/mole]/RT
Bath gas:   Ethanol, 2-(dimethylphenylsilyl)-, acetate
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
593 6.47E-4
600 9.77E-4
625 3.96E-3
650 1.44E-2
670 3.79E-2