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Accessibility information
Author(s):   Lifshitz, A.; Tamburu, C.; Suslensky, A.
Title:   Isomerization and decomposition of pyrrole at elevated temperatures. Studies with a single-pulse shock tube
Journal:   J. Phys. Chem.
Volume:   93
Page(s):   5802 - 5808
Year:   1989
Reference type:   Journal article
Squib:   1989LIF/TAM5802-5808

Reaction:   Pyrrole → Other Products + C2H2
Reaction order:   1
Temperature:   1080 - 1280 K
Pressure:  1.01 bar
Rate expression:   1.91x1014 [s-1] e-321770 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1080 5.23E-2
1100 1.00E-1
1125 2.19E-1
1150 4.64E-1
1175 9.48E-1
1200 1.88E0
1225 3.64E0
1250 6.84E0
1275 1.26E1
1280 1.41E1