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Accessibility information
Author(s):   Sullivan, J.H.
Title:   Deuterium kinetic isotope effect in the hydrogen-iodine reaction
Journal:   J. Chem. Phys.
Volume:   39
Year:   1963
Reference type:   Journal article
Squib:   1963SUL3001

Reaction:   H2 + IHI +
Reaction order:   2
Reference reaction:   D2 + IDI + D
Reference reaction order:   2
Temperature:   633 - 800 K
Pressure:  8.00E-3 - 0.74 bar
Rate expression:   1.33 e4265 [±8314472 J/mole]/RT
Uncertainty:   1.10000002
Bath gas:   D2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
633 2.99E0
650 2.93E0
675 2.84E0
700 2.77E0
725 2.70E0
750 2.64E0
775 2.58E0
800 2.53E0