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Author(s):   Gordon, A.S.
Title:   A study of some reactions of the cyclopentyl radical
Journal:   Can. J. Chem.
Volume:   43
Year:   1965
Reference type:   Journal article
Squib:   1965GOR570

Reaction:   CyclopentylC2H4 + ·CH2CH=CH2
Reaction order:   1
Temperature:   585 - 680 K
Pressure:  6.40E-2 - 0.16 bar
Rate expression:   3.16x1014 [s-1] e-157975 [J/mole]/RT
Bath gas:   (CD3)2CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
585 2.48E0
600 5.59E0
625 1.98E1
650 6.38E1
675 1.88E2
680 2.32E2