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Accessibility information
Author(s):   Foon, R.; Tait, K.B.
Title:   Chlorine abstraction reactions of fluorine. Part 2 - The kinetic determination of the bond dissociation energy D° (Cl2F---Cl)
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   68
Year:   1972
Reference type:   Journal article
Squib:   1972FOO/TAI104

Reaction:   CFCl3 + ·F·CCl2F + ClF
Reaction order:   2
Temperature:   491 - 586 K
Pressure:  5.33E-2 - 0.49 bar
Rate expression:   4.78x10-12 [cm3/molecule s] e-54294 [±543 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
491 8.01E-18
500 1.02E-17
525 1.90E-17
550 3.34E-17
575 5.59E-17
586 6.92E-17