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Author(s):   Kaiser, E.W.; Wallington, T.J.; Hurley, M.D.
Title:   Products and Mechanism of the Reaction of Cl with Butanone in N2/O2 Diluent at 297-526 K
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   2424 - 2437
Year:   2009
Reference type:   Journal article
Squib:   2009KAI/WAL2424-2437

Reaction:   C2H5COCH3 + ·Cl → Products
Reaction order:   2
Reference reaction:   C2H6 + ·Cl·C2H5 + HCl
Temperature:   297 - 475 K
Pressure:  0.93 - 1.20 bar
Rate expression:   4.0x10-11 [±3.0x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Gas chromatography and FTIR were used for product analysis. The uncertainty quoted in the abstract is larger, ± 0.4 cm3 molecule-1 s-1. The experimental activation energy is zero with the quoted uncertainty of 200 cal/mol.

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