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Author(s):   Vedeneev, V.I.; Teitel'boim, M.A.; Shoikhet, A.A.
Title:   The photolysis of CF3I in the presence of O2 and Br2. 1. The mechanism of the elementary step in the reaction of CF3 radicals with O2
Journal:   Bull. Acad. Sci. USSR Div. Chem. Sci. (Engl. Transl.)
Volume:   8
Page(s):   1534 - 1537
Year:   1978
Reference type:   Journal article
Squib:   1978VED/TEI1534-1537

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1978VED/TEI1534-1537   ·CF3 + F2 → CF4 + ·F  296   2.51E-14              2
  1978VED/TEI1534-1537   ·CF3 + O2 → CF3O2  296   1.50E-12              2
  1978VED/TEI1534-1537   ·CF3 + O2 → CF3O2  296   2.90              2
  Reference reaction:  ·CF3 + Br2 → CF3Br + Br· 2
Search returned 3 records.