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Accessibility information
Author(s):   Rao, V.S.; Skinner, G.B.
Title:   Reactions of vinyl radicals at high temperatures: Pyrolysis of vinyl bromide and vinyl iodide and the reaction H + C2D2 →’ D + C2HD
Journal:   J. Phys. Chem.
Volume:   92
Year:   1988
Reference type:   Journal article
Squib:   1988RAO/SKI6313

Reaction:   C2H3C2H2 +
Reaction order:   1
Temperature:   1200 - 1900 K
Pressure:  0.51 bar
Rate expression:   6.93x1012 [s-1] e-186244 [J/mole]/RT
Bath gas:   Ar
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1200 5.42E4
1250 1.14E5
1300 2.28E5
1350 4.31E5
1400 7.80E5
1450 1.35E6
1500 2.27E6
1550 3.67E6
1600 5.76E6
1650 8.81E6
1700 1.31E7
1750 1.91E7
1800 2.73E7
1850 3.82E7
1900 5.26E7