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Accessibility information
Author(s):   Rao, V.S.; Skinner, G.B.
Title:   Reactions of vinyl radicals at high temperatures: Pyrolysis of vinyl bromide and vinyl iodide and the reaction H + C2D2 →’ D + C2HD
Journal:   J. Phys. Chem.
Volume:   92
Year:   1988
Reference type:   Journal article
Squib:   1988RAO/SKI6313

Reaction:   C2H3C2H2 +
Reaction order:   2
Temperature:   1380 - 1750 K
Pressure:  0.51 bar
Rate expression:   1.16x10-10 [cm3/molecule s] e-117234 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1380 4.25E-15
1400 4.91E-15
1425 5.86E-15
1450 6.95E-15
1475 8.20E-15
1500 9.62E-15
1525 1.12E-14
1550 1.30E-14
1575 1.50E-14
1600 1.73E-14
1625 1.98E-14
1650 2.26E-14
1675 2.57E-14
1700 2.91E-14
1725 3.28E-14
1750 3.68E-14