Author(s):   Oehlschlaeger, M.A.; Davidson, D.F.; Hanson, R.K.
Title:   High-temperature thermal decomposition of isobutane and n-butane behind shock waves
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   4247 - 4253
Year:   2004
Reference type:   Journal article
Squib:   2004OEH/DAV4247-4253

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	Order
2004OEH/DAV4247-4253	iso-C₄H₁₀ → 2-C₃H₇ + ·CH₃	1310 - 1551			1
2004OEH/DAV4247-4253	1-C₄H₁₀ → ·C₂H₅ + ·C₂H₅	1297 - 1601			1
2004OEH/DAV4247-4253	1-C₄H₁₀ → 1-C₃H₇ + ·CH₃	1297 - 1601			1
2004OEH/DAV4247-4253	iso-C₄H₁₀ → 2-C₃H₇ + ·CH₃	1320 - 1560	4.83E16	3.34E05	1
2004OEH/DAV4247-4253	iso-C₄H₁₀ → 2-C₃H₇ + ·CH₃	1320 - 1560	4.00E-05	2.20E05	2
2004OEH/DAV4247-4253	1-C₄H₁₀ → 1-C₃H₇ + ·CH₃	1320 - 1600	8.87E-07	1.80E05	2
2004OEH/DAV4247-4253	1-C₄H₁₀ → 1-C₃H₇ + ·CH₃	1320 - 1600	4.28E14	2.93E05	1
2004OEH/DAV4247-4253	1-C₄H₁₀ → ·C₂H₅ + ·C₂H₅	1320 - 1600	2.72E15	3.16E05	1
2004OEH/DAV4247-4253	1-C₄H₁₀ → ·C₂H₅ + ·C₂H₅	1320 - 1600	7.84E-06	2.07E05	2

Search returned 9 records.