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Author(s):   Oehlschlaeger, M.A.; Davidson, D.F.; Hanson, R.K.
Title:   High-temperature thermal decomposition of isobutane and n-butane behind shock waves
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   4247 - 4253
Year:   2004
Reference type:   Journal article
Squib:   2004OEH/DAV4247-4253

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
    2004OEH/DAV4247-4253   iso-C4H102-C3H7 + ·CH3  1310 - 1551                  1
    2004OEH/DAV4247-4253   1-C4H10·C2H5 + ·C2H5  1297 - 1601                  1
    2004OEH/DAV4247-4253   1-C4H101-C3H7 + ·CH3  1297 - 1601                  1
  2004OEH/DAV4247-4253   iso-C4H102-C3H7 + ·CH3  1320 - 1560   4.83E16       3.34E05      1
  2004OEH/DAV4247-4253   iso-C4H102-C3H7 + ·CH3  1320 - 1560   4.00E-05       2.20E05      2
  2004OEH/DAV4247-4253   1-C4H101-C3H7 + ·CH3  1320 - 1600   8.87E-07       1.80E05      2
  2004OEH/DAV4247-4253   1-C4H101-C3H7 + ·CH3  1320 - 1600   4.28E14       2.93E05      1
  2004OEH/DAV4247-4253   1-C4H10·C2H5 + ·C2H5  1320 - 1600   2.72E15       3.16E05      1
  2004OEH/DAV4247-4253   1-C4H10·C2H5 + ·C2H5  1320 - 1600   7.84E-06       2.07E05      2

Search returned 9 records.