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Title: Atmospheric reactions of methylcyclohexanes with Cl atoms and OH radicals: determination of rate coefficients and degradation products
Journal: Environ. Sci. Pollut. Res.
Volume: 22
Page(s): 4806 - 4819
Year: 2015
Reference type: Journal article
Squib: 2015BAL/CEA4806-4819
Reaction:
trans-1,4-Dimethylcyclohexane + ·Cl → Products
Reaction order:
2
Temperature:
298
K
Pressure: 0.96 bar
Rate expression:
2.89x10-10 [±2.6x10-11 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
GC-MS
Comments:
The reported error is twice the standard deviation. GC/MS and FTIR were used for species detection. Tetrahydro-2H-pyran, hextane, cyclohexane, and propene were used as reference compounds.
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