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Author(s):   Ballesteros, B.; Ceacero-Vega, A. A.; Jimenez, E.; Albaladejo, J.
Title:   Atmospheric reactions of methylcyclohexanes with Cl atoms and OH radicals: determination of rate coefficients and degradation products
Journal:   Environ. Sci. Pollut. Res.
Volume:   22
Page(s):   4806 - 4819
Year:   2015
Reference type:   Journal article
Squib:   2015BAL/CEA4806-4819

Reaction:   cis-1,4-Dimethylcyclohexane + ·Cl → Products
Reaction order:   2
Temperature:   298 K
Pressure:  0.96 bar
Rate expression:   2.89x10-10 [±1.6x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   GC-MS
Comments:   The reported error is twice the standard deviation. GC/MS and FTIR were used for species detection. Tetrahydro-2H-pyran, 1-butene, 1,3-butadiene, and cyclohexane were used as reference compounds.

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