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Author(s):   Awan, I.A.; McGivern, W.S.; Tsang, W.; Manion, J.A.
Title:   Decomposition and Isomerization of 5-Methylhex-1-yl Radical
Journal:   J. Phys. Chem. A
Volume:   114
Page(s):   7832 - 7846
Year:   2010
Reference type:   Journal article
Squib:   2010AWA/MCG7832-7846

Reaction:   CH3CH2CH2CH(·)CH(CH3)2 → ·CH3 + (Z)-2-C6H12
Reaction order:   2
Reference reaction:   CH3CH2CH2CH(·)CH(CH3)2 → ·CH3 + (E)-2-C6H12
Reference reaction order:   2
Temperature:   889 - 1064 K
Pressure:  1.20 - 2.20 bar
Rate expression:   3.09 e-3742 [±1497 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Errors are given as the standard uncertainties (1σ) derived from the statistical fits. The uncertainty in the preexponential factor is expressed as follows: A = 10(0.49±0.08).

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
889 1.86E0
900 1.87E0
925 1.90E0
950 1.92E0
975 1.95E0
1000 1.97E0
1025 1.99E0
1050 2.01E0
1064 2.02E0