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Title: Decomposition and Isomerization of 5-Methylhex-1-yl Radical
Journal: J. Phys. Chem. A
Volume: 114
Page(s): 7832 - 7846
Year: 2010
Reference type: Journal article
Squib: 2010AWA/MCG7832-7846
Reaction:
CH3CH2CH2CH(·)CH(CH3)2 → ·CH3 + (Z)-2-C6H12
Reaction order:
2
Reference reaction:
CH3CH2CH2CH(·)CH(CH3)2 → ·CH3 + (E)-2-C6H12
Reference reaction order:
2
Temperature:
889 - 1064
K
Pressure: 1.20 - 2.20 bar
Rate expression:
3.09 e-3742 [±1497 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
Rate constant is pressure independent
Experimental procedure:
Shock tube
Excitation technique:
Thermal
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
Comments:
Errors are given as the standard uncertainties (1σ) derived from the statistical fits. The uncertainty in the preexponential factor is expressed as follows: A = 10(0.49±0.08).
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Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 889 | 1.86E0 |
| 900 | 1.87E0 |
| 925 | 1.90E0 |
| 950 | 1.92E0 |
| 975 | 1.95E0 |
| 1000 | 1.97E0 |
| 1025 | 1.99E0 |
| 1050 | 2.01E0 |
| 1064 | 2.02E0 |