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Accessibility information
Author(s):   McIntyre, J.A.; Diesen, R.W.
Title:   Mass spectral study of the decomposition of chlorine fluoride behind shock waves
Journal:   J. Phys. Chem.
Volume:   75
Year:   1971
Reference type:   Journal article
Squib:   1971MCI/DIE1765

Reaction:   ClF·F + ·Cl
Reaction order:   2
Temperature:   2000 - 2950 K
Rate expression:   1.32x10-11 [cm3/molecule s] e-173772 [±8314472 J/mole]/RT
Uncertainty:   2.50999999
Bath gas:   Ne
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
2000 3.82E-16
2050 4.92E-16
2100 6.28E-16
2150 7.91E-16
2200 9.87E-16
2250 1.22E-15
2300 1.49E-15
2350 1.81E-15
2400 2.18E-15
2450 2.60E-15
2500 3.09E-15
2550 3.64E-15
2600 4.26E-15
2650 4.95E-15
2700 5.73E-15
2750 6.60E-15
2800 7.56E-15
2850 8.61E-15
2900 9.78E-15
2950 1.10E-14