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Accessibility information
Author(s):   Rudich, Y.; Talukdar, R.K.; Fox, R.W.; Ravishankara, A.R.
Title:   Rate coefficients for reactions of NO3 with a few olefins and oxygenated olefins
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   5374 - 5381
Year:   1996
Reference type:   Journal article
Squib:   1996RUD/TAL5374-5381

Reaction:   (E)-2-C4H8 + NO3 → Products
Reaction order:   2
Temperature:   267 - 298 K
Pressure:  2.00E-3 - 4.00E-3 bar
Rate expression:   1.29x10-12 [cm3/molecule s] e-2868 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
267 3.54E-13
275 3.68E-13
298 4.05E-13