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Title: Mechanisms of the homogeneous, unimolecular gas-phase elimination kinetics of triethyl orthoacetate and triethyl orthopropionate
Journal: J. Phys. Org. Chem.
Volume: 21
Page(s): 666 - 669
Year: 2008
Reference type: Journal article
Squib: 2008MAR/TOS666-669
Reaction:
Propane, 1,1,1-triethoxy- → C2H5OH + C2H4 + C2H5C(O)OC2H5
Reaction order:
1
Temperature:
564 - 624
K
Pressure: 0.11 - 0.23 bar
Rate expression:
4.27x1013 [±7.0x1011 s-1] e-193300 [±1800 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 564 | 5.35E-5 |
| 575 | 1.18E-4 |
| 600 | 6.35E-4 |
| 624 | 2.82E-3 |