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Author(s):   Chaudhry, A.U.; Gowenlock, B.G.
Title:   Arrhenius parameters for the reactions of methyl radicals with group IV tetramethyls
Journal:   J. Organometal. Chem.
Volume:   16
Year:   1969
Reference type:   Journal article
Squib:   1969CHA/GOW221

Reaction:   (CH3)4Sn + ·CH3CH4 + (CH3)3SnCH2·
Reaction order:   2
Temperature:   393 - 433 K
Rate expression:   2.09x10-13 [cm3/molecule s] e-36002 [±1081 J/mole]/RT
Uncertainty:   1.35000002
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
393 3.43E-18
400 4.16E-18
425 7.87E-18
433 9.50E-18