Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: The thermal decomposition of n-butyl vinyl ether. Part 1. The inhibited reaction
Journal: J. Chem. Soc. B
Page(s): 523 - 524
Year: 1967
Reference type: Journal article
Squib: 1967BAM/EMO523-524
Reaction:
n-C4H9OCH=CH2 → CH3CHO + 1-C4H8
Reaction order:
1
Temperature:
590 - 650
K
Pressure: 0.11 - 0.46 bar
Rate expression:
1.42x1011 [±1.4x109 s-1] e-177098 [±172110 J/mole]/RT
Bath gas:
Cyclohexene
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 590 | 2.98E-5 |
| 600 | 5.43E-5 |
| 625 | 2.25E-4 |
| 650 | 8.33E-4 |