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Title: The mechanisms of thermal eliminations. Part 12. Relative rates of pyrolysis of ethyl, isopropyl, t-butyl, and n-butyl, vinyl ethers: Rate spread as an index of elimination mechanisms
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s):
Year: 1982
Reference type: Journal article
Squib: 1982MCE/TAY1179
Reaction:
n-C4H9OCH=CH2 → CH3CHO + 1-C4H8
Reaction order:
1
Temperature:
595 - 681
K
Rate expression:
1.92x1011 [s-1] e-177930 [J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 595 | 4.61E-5 |
| 600 | 6.22E-5 |
| 625 | 2.59E-4 |
| 650 | 9.66E-4 |
| 675 | 3.27E-3 |
| 681 | 4.32E-3 |