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Accessibility information
Author(s):   Hoyermann, K.; Seeba, J.
Title:   Mechanism and rate of the reaction of cyanomethyl radicals with oxygen atoms in the gas phase
Journal:   Z. Phys. Chem. (Munich)
Volume:   188
Page(s):   215 - 226
Year:   1995
Reference type:   Journal article
Squib:   1995HOY/SEE215-226

Reaction:   CH2CN + → Products
Reaction order:   2
Reference reaction:   ·CH3 + → Products
Temperature:   253 - 353 K
Pressure:  5.07E-4 - 1.00E-2 bar
Rate expression:   8.49x10-11 [cm3/molecule s] (T/298 K)0.64
Bath gas:   He
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
253 7.64E-11
275 8.06E-11
300 8.52E-11
325 8.97E-11
350 9.41E-11
353 9.46E-11