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Author(s):   Nicovich, J.M.; Van Dijk, C.A.; Kreutter, K.D.; Wine, P.H.
Title:   Kinetics of the reactions of alkyl radicals with HBr and DBr
Journal:   J. Phys. Chem.
Volume:   95
Page(s):   9890 - 9896
Year:   1991
Reference type:   Journal article
Squib:   1991NIC/VAN9890-9896

Reaction:   tert-C4H9 + HBriso-C4H10 + Br·
Reaction order:   2
Temperature:   297 - 429 K
Pressure:  1.33E-2 - 4.00E-2 bar
Rate expression:   1.07x10-12 [±3.49x10-13 cm3/molecule s] e8007 [±1280 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
297 2.74E-11
300 2.65E-11
325 2.07E-11
350 1.68E-11
375 1.39E-11
400 1.19E-11
425 1.03E-11
429 1.01E-11