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Author(s):   Glaenzer, K.; Troe, J.
Title:   Thermische Zerfallsreaktionen von Nitroverbindungen in Stosswellen. II. Dissoziation von Nitroaethan
Journal:   Helv. Chim. Acta
Volume:   56
Year:   1973
Reference type:   Journal article
Squib:   1973GLA/TRO577

Reaction:   C2H5NO2·C2H5 + NO2
Reaction order:   1
Temperature:   900 - 1350 K
Pressure:  4.00E-2 - 1.60 bar
Rate expression:   7.94x1015 [s-1] e-238625 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
900 1.12E2
925 2.66E2
950 6.02E2
975 1.31E3
1000 2.73E3
1025 5.49E3
1050 1.07E4
1075 2.02E4
1100 3.70E4
1125 6.61E4
1150 1.15E5
1175 1.96E5
1200 3.26E5
1225 5.31E5
1250 8.48E5
1275 1.33E6
1300 2.05E6
1325 3.11E6
1350 4.65E6