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Title: Thermische Zerfallsreaktionen von Nitroverbindungen in Stosswellen. II. Dissoziation von Nitroaethan
Journal: Helv. Chim. Acta
Volume: 56
Page(s):
Year: 1973
Reference type: Journal article
Squib: 1973GLA/TRO577
Reaction:
C2H5NO2 → ·C2H5 + NO2
Reaction order:
1
Temperature:
900 - 1350
K
Pressure: 4.00E-2 - 1.60 bar
Rate expression:
7.94x1015 [s-1] e-238625 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Thermal
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 900 | 1.12E2 |
| 925 | 2.66E2 |
| 950 | 6.02E2 |
| 975 | 1.31E3 |
| 1000 | 2.73E3 |
| 1025 | 5.49E3 |
| 1050 | 1.07E4 |
| 1075 | 2.02E4 |
| 1100 | 3.70E4 |
| 1125 | 6.61E4 |
| 1150 | 1.15E5 |
| 1175 | 1.96E5 |
| 1200 | 3.26E5 |
| 1225 | 5.31E5 |
| 1250 | 8.48E5 |
| 1275 | 1.33E6 |
| 1300 | 2.05E6 |
| 1325 | 3.11E6 |
| 1350 | 4.65E6 |