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Author(s):   Finlayson-Pitts, B.J.; Ezell, M.J.; Wang, S.Z.; Grant, C.E.
Title:   Reaction of OH with ClNO: Kinetics and mechanisms
Journal:   J. Phys. Chem.
Volume:   91
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987FIN/EZE2377

Reaction:   NOCl + ·OH → Products
Reaction order:   2
Temperature:   262 - 373 K
Pressure:  1.33E-3 bar
Rate expression:   1.5x10-12 [±1.05x10-13 cm3/molecule s] e-3808 [±229 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Resonance fluorescence

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
262 2.61E-13
275 2.84E-13
300 3.26E-13
325 3.67E-13
350 4.06E-13
373 4.40E-13