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Author(s):   Bedjanian, Y.
Title:   Kinetics and Products of the Reaction of OH Radicals with CINO from 220 to 940 K
Journal:   J. Phys. Chem. A
Volume:   122
Page(s):   916 - 922
Year:   2018
Reference type:   Journal article
Squib:   2018BED916-922

Reaction:   NOCl + ·OH → Products
Reaction order:   2
Temperature:   220 - 940 K
Pressure:  2.67E-3 bar
Rate expression:   2.6x10-13 [cm3/molecule s] (T/298 K)2.12 e1214 [J/mole]/RT
Uncertainty:   1.14999998
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   HOCl, Cl, and HONO were observed as the reaction products.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
220 2.66E-13
250 3.22E-13
300 4.30E-13
350 5.56E-13
400 7.00E-13
450 8.63E-13
500 1.04E-12
550 1.24E-12
600 1.46E-12
650 1.70E-12
700 1.96E-12
750 2.24E-12
800 2.54E-12
850 2.85E-12
900 3.19E-12
940 3.47E-12