Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article



Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Gonzalez, A.C.; Larson, C.W.; McMillen, D.F.; Golden, D.M.
Title:   Mechanism of decomposition of nitroaromatics. Laser-powered homogeneous pyrolysis of substituted nitrobenzenes
Journal:   J. Phys. Chem.
Volume:   89
Year:   1985
Reference type:   Journal article
Squib:   1985GON/LAR4809

Reaction:   NitrobenzenePhenyl + NO2
Reaction order:   1
Reference reaction:   CyclohexeneC2H4 + 1,3-Butadiene
Temperature:   1110 - 1250 K
Pressure:  0.15 bar
Rate expression:   3.16x1015 [s-1] e-286018 [±5712 J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   SF6
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1110 1.10E2
1125 1.66E2
1150 3.23E2
1175 6.10E2
1200 1.12E3
1225 2.01E3
1250 3.53E3