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Author(s):   Gonzalez, A.C.; Larson, C.W.; McMillen, D.F.; Golden, D.M.
Title:   Mechanism of decomposition of nitroaromatics. Laser-powered homogeneous pyrolysis of substituted nitrobenzenes
Journal:   J. Phys. Chem.
Volume:   89
Page(s):  
Year:   1985
Reference type:   Journal article
Squib:   1985GON/LAR4809

Reaction:   NitrobenzenePhenyl + NO2
Reaction order:   1
Reference reaction:   CyclohexeneC2H4 + 1,3-Butadiene
Temperature:   1110 - 1250 K
Pressure:  0.15 bar
Rate expression:   3.16x1015 [s-1] e-286018 [±5712 J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   SF6
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1110 1.10E2
1125 1.66E2
1150 3.23E2
1175 6.10E2
1200 1.12E3
1225 2.01E3
1250 3.53E3