Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: The mechanism of the gas-phase pyrolysis of esters. Part 13. The very strong activating effects of β-trialkylmetal groups
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s): 1313 - 1319
Year: 1982
Reference type: Journal article
Squib: 1982EAB/MAH1313-1319
Reaction:
Benzenemethanol, 3-chloro-α-[(trimethylsilyl)methyl]-, acetate → Silane, [2-(3-chlorophenyl)ethenyl]trimethyl- + CH3C(O)OH
Reaction order:
1
Temperature:
570 - 620
K
Rate expression:
5.25x1012 [s-1] e-160469 [J/mole]/RT
Bath gas:
Benzenemethanol, 3-chloro-α-[(trimethylsilyl)methyl]-, acetate
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 570 | 1.04E-2 |
| 575 | 1.39E-2 |
| 600 | 5.63E-2 |
| 620 | 1.59E-1 |