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Title: Temperature dependence of rate coefficients of reactions of NO2 with CH3S and C2H5S
Journal: J. Phys. Chem. A
Volume: 104
Page(s): 5525 - 5529
Year: 2000
Reference type: Journal article
Squib: 2000CHA/WAN5525-5529
Reaction:
NO2 + CH3CH2S → Products
Reaction order:
1
Temperature:
223 - 402
K
Pressure: 1.33 bar
Rate expression:
2.4x10-10 [±7.0x10-11 s-1] e-1746 [±665 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 223 | 9.36E-11 |
| 225 | 9.44E-11 |
| 250 | 1.04E-10 |
| 275 | 1.12E-10 |
| 300 | 1.19E-10 |
| 325 | 1.26E-10 |
| 350 | 1.32E-10 |
| 375 | 1.37E-10 |
| 400 | 1.42E-10 |
| 402 | 1.42E-10 |