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Accessibility information
Author(s):   Anastasi, C.; Waddington, D.J.; Woolley, A.
Title:   Reactions of oxygenated radicals in the gas phase. Part 10. -Self-reactions of ethylperoxy radicals
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   79
Page(s):  
Year:   1983
Reference type:   Journal article
Squib:   1983ANA/WAD505

Reaction:   C2H5OO· + C2H5OO· → Other Products + C2H5OH
Reaction order:   2
Reference reaction:   C2H5OO· + C2H5OO· → Other Products + CH3CH2O·
Temperature:   302 - 373 K
Pressure:  1.01 bar
Rate expression:   5.8x10-14 [±2.99x10-14 cm3/molecule s] e-2627 [±1389 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
302 2.04E-14
325 2.19E-14
350 2.35E-14
373 2.48E-14