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Title: Kinetics of the gas-phase reactions of NO3 radicals with ethyl acrylate, n-butyl acrylate, methyl methacrylate and ethyl methacrylate
Journal: Atmos. Environ.
Volume: 44
Page(s): 1847 - 1850
Year: 2010
Reference type: Journal article
Squib: 2010WAN/GE1847-1850
Reaction:
Methyl methacrylate + NO3 → Products
Reaction order:
2
Reference reaction:
1-C4H8 + NO3 → Products
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
3.72x10-15 [±1.15x10-15 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Thermal
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
Comments:
The error in the value of the rate constant is a combination of 2σ from the least-squares analysis and the uncertainty in the rate constant of the reference reaction.
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