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Author(s):   Zhou, L.; Ravishankara, A.R.; Brown, S.S.; Idir, M.; Zarzana, K.J.; Daele, V.; Mellouki, A.
Title:   Kinetics of the Reactions of NO3 Radical with Methacrylate Esters
Journal:   J. Phys. Chem. A
Volume:   121
Page(s):   4464 - 4474
Year:   2017
Reference type:   Journal article
Squib:   2017ZHO/RAV4464-4474

Reaction:   Methyl methacrylate + NO3 → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   2.92x10-15 [±3.7x10-16 cm3/molecule s]
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Temporal profiles of NO3 and N2O5 were followed by using a dual channel cavity ring-down spectrometer. The quoted errors include estimated systematic errors.

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