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Author(s):
Zhou, L.; Ravishankara, A.R.; Brown, S.S.; Idir, M.; Zarzana, K.J.; Daele, V.; Mellouki, A.
Title:
Kinetics of the Reactions of NO3 Radical with Methacrylate Esters
Journal:
J. Phys. Chem. A
Volume:
121
Page(s):
4464 - 4474
Year:
2017
Reference type:
Journal article
Squib:
2017ZHO/RAV4464-4474
Reaction:
Methyl methacrylate + NO3 → Products
Reaction order:
2
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
2.98x10-15 [±3.5x10-16 cm3/molecule s]
Category: Experiment
Data type:
Experimental value and limited review
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Thermal
Comments:
Two different experimental methods (relative rate and absolute rate methods) were used. The quoted values are the weighted averages from these two methods. The quoted uncertainties are at the 2σ level and include estimated systematic errors.
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