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Accessibility information
Author(s):   Zaslonko, I.S.; Mukoseev, Yu.K.
Title:   Thermal decomposition of SiCl4 in shock waves
Journal:   Kinet. Catal. (Engl. Transl.)
Volume:   38
Page(s):   325 - 329
Original page:   357
Year:   1997
Reference type:   Journal article
Squib:   1997ZAS/MUK325-329

Reaction:   SiCl4SiCl3 + ·Cl
Reaction order:   2
Temperature:   1600 - 2600 K
Rate expression:   5.11x10-8 [cm3/molecule s] e-325096 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1600 1.25E-18
1700 5.25E-18
1800 1.88E-17
1900 5.91E-17
2000 1.65E-16
2100 4.19E-16
2200 9.78E-16
2300 2.12E-15
2400 4.30E-15
2500 8.25E-15
2600 1.51E-14