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Accessibility information
Author(s):   Galiba, I.; Tedder, J.M.; Watson, R.A.
Title:   Free-radical substitution in aliphatic compounds. Part V. The halogenation of 1,1,1-trifluoropentane
Journal:   J. Chem. Soc. A
Page(s):  
Year:   1964
Reference type:   Journal article
Squib:   1964GAL/TED1321

Reaction:   1-C4H10 + Br· → sec-C4H9 + HBr
Reaction order:   2
Temperature:   298 - 503 K
Rate expression:   6.61x10-11 [cm3/molecule s] e-42653 [J/mole]/RT
Bath gas:   N2
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.21E-18
300 2.48E-18
325 9.22E-18
350 2.85E-17
375 7.57E-17
400 1.78E-16
425 3.78E-16
450 7.40E-16
475 1.35E-15
500 2.31E-15
503 2.46E-15