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Title: Kinetics of the vapour-phase bromination of cyclanes and n-butane. C-H bond dissociation energies in cyclanes
Journal: Trans. Faraday Soc.
Volume: 67
Page(s):
Year: 1971
Reference type: Journal article
Squib: 1971FER/WHI2618
Reaction:
1-C4H10 + Br· → sec-C4H9 + HBr
Reaction order:
2
Reference reaction:
Cyclopentane + Br· → Cyclopentyl + HBr
Reference reaction order:
2
Temperature:
319 - 468
K
Pressure: 0.11 - 0.22 bar
Rate expression:
1.41 e-5097 [±8314472 J/mole]/RT
Uncertainty:
1.08000004
Bath gas:
1-C4H10
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 319 | 2.06E-1 |
| 325 | 2.14E-1 |
| 350 | 2.45E-1 |
| 375 | 2.75E-1 |
| 400 | 3.05E-1 |
| 425 | 3.33E-1 |
| 450 | 3.61E-1 |
| 468 | 3.81E-1 |