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Author(s):   Tyndall, G.S.; Orlando, J.J.; Kegley-Owen, C.S.; Wallington, T.J.; Hurley, M.D.
Title:   Rate Coefficients for the Reactions of Chlorine Atoms with Methanol and Acetaldehyde
Journal:   Int J. Chem. Kinet.
Volume:   31
Page(s):   776 - 784
Year:   1999
Reference type:   Journal article
Squib:   1999TYN/ORL776-784

Reaction:   CH3OH + ·Cl(·)CH2OH + HCl
Reaction order:   2
Temperature:   295 K
Pressure:  0.93 bar
Rate expression:   5.4x10-11 [±9.0x10-1 cm3/molecule s]
Uncertainty:   0.0500000007
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Resonance fluorescence
Comments:   The rate constant was also measured by relative rate method, is consistent with the literature vlaues.

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