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Author(s):   Seakins, P.W.; Orlando, J.J.; Tyndall, G.S.
Title:   Rate coefficients and production of vibrationally excited HCl from the reactions of chlorine atoms with methanol, ethanol, acetaldehyde and formaldehyde
Journal:   Phys. Chem. Chem. Phys.
Volume:   6
Page(s):   2224 - 2229
Year:   2004
Reference type:   Journal article
Squib:   2004SEA/ORL2224-2229

Reaction:   CH3OH + ·Cl(·)CH2OH + HCl
Reaction order:   2
Temperature:   298 K
Pressure:  3.33E-2 bar
Rate expression:   5.83x10-11 [±7.7x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   IR absorption

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