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Author(s):   Wojcik-Pastuszka, D.; Jodkowski, J.T.
Title:   Spectrokinetic Study of the Reaction System of 2NO 2<-> N2O4 with Butanols Between 320-358 K in the Gas Phase
Journal:   Pol. J. Chem.
Volume:   83
Page(s):   131 - 143
Year:   2009
Reference type:   Journal article
Squib:   2009WOJ/JOD131-143

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2009WOJ/JOD131-143   CH3CH2CH2CH2OH + N2O4 → n-C4H9ONO + HNO3  298   3.90E-18           3.90E-18  2
  2009WOJ/JOD131-143   sec-C4H9OH + N2O4 → CH3CH2CH(CH3)ONO + HNO3  298   1.70E-18           1.70E-18  2
  2009WOJ/JOD131-143   iso-C4H9OH + N2O4 → (CH3)2CHCH2ONO + HNO3  298   4.20E-18           4.20E-18  2
  2009WOJ/JOD131-143   tert-C4H9OH + N2O4 → (CH3)3CONO + HNO3  298   5.70E-18           5.70E-18  2
  2009WOJ/JOD131-143   n-C4H9ONO + HNO3 → CH3CH2CH2CH2OH + N2O4  298   3.00E-21           3.00E-21  2
  2009WOJ/JOD131-143   CH3CH2CH(CH3)ONO + HNO3 → sec-C4H9OH + N2O4  298   2.30E-20           2.30E-20  2
  2009WOJ/JOD131-143   (CH3)2CHCH2ONO + HNO3 → iso-C4H9OH + N2O4  298   4.00E-21           4.00E-21  2
  2009WOJ/JOD131-143   (CH3)3CONO + HNO3 → tert-C4H9OH + N2O4  298   2.30E-20           2.30E-20  2
  2009WOJ/JOD131-143   n-C4H9ONO + HNO3 → N2O4 + (C2H5)2NO  320 - 358   9.92E-14       4.29E04      2
  2009WOJ/JOD131-143   CH3CH2CH(CH3)ONO + HNO3 → sec-C4H9OH + N2O4  320 - 358   6.00E-15       3.09E04      2
  2009WOJ/JOD131-143   (CH3)2CHCH2ONO + HNO3 → iso-C4H9OH + N2O4  320 - 358   4.66E-17       2.32E04      2
  2009WOJ/JOD131-143   (CH3)3CONO + HNO3 → tert-C4H9OH + N2O4  320 - 358   7.08E-17       1.99E04      2
  2009WOJ/JOD131-143   CH3CH2CH2CH2OH + N2O4 → n-C4H9ONO + HNO3  320 - 358   6.85E-17       7100      2
  2009WOJ/JOD131-143   sec-C4H9OH + N2O4 → CH3CH2CH(CH3)ONO + HNO3  320 - 358   1.04E-13       2.73E04      2
  2009WOJ/JOD131-143   iso-C4H9OH + N2O4 → (CH3)2CHCH2ONO + HNO3  320 - 358   1.65E-15       1.48E04      2
  2009WOJ/JOD131-143   tert-C4H9OH + N2O4 → (CH3)3CONO + HNO3  320 - 358   1.69E-15       1.41E04      2
Search returned 16 records.