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Author(s):   Solly, R.K.; Benson, S.W.
Title:   Kinetics of the gas-phase unimolecular decomposition of the benzoyl radical
Journal:   J. Am. Chem. Soc.
Volume:   93
Page(s):  
Year:   1971
Reference type:   Journal article
Squib:   1971SOL/BEN2127

Reaction:   benzoyl → CO + Phenyl
Reaction order:   1
Temperature:   614 - 667 K
Pressure:  3.20E-2 - 0.61 bar
Rate expression:   3.98x1014 [s-1] e-123054 [±7383 J/mole]/RT
Uncertainty:   3.16000009
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
614 1.35E4
625 2.07E4
650 5.14E4
667 9.19E4