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©NIST, 2013
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Author(s):   Honma, K.; Hirata, D.
Title:   Reaction dynamics of Al + CO2 -> AlO plus CO studied by a crossed-beam velocity map imaging technique
Journal:   J. Chem. Phys.
Volume:   147
Year:   2017
Reference type:   Journal article
Squib:   2017HON/HIR013903

Reaction:   CO2 + AlCO + AlO
Reaction order:   2
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Pressure dependence:   None reported
Experimental procedure:   Molecular beam
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The oxidation reaction of a gas-phase aluminum atom by a carbon dioxide molecule was studied by employing a crossed-beam technique at two collision energies: 27.9 and 52.8 kJ/mol. The results suggested that the reaction proceeds via a short-lived intermediate in which the O–C–O keeps a nearly linear structure.

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