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Title: Rate constants for the interaction of trifluoromethyl radicals with oxygen and fluorine
Journal: React. Kinet. Catal. Lett.
Volume: 6
Page(s): 161 - 167
Year: 1977
Reference type: Journal article
Squib: 1977ARU/GOR161-167
Reaction:
·CF3 + O2 → CF3O2
Reaction order:
2
Reference reaction:
·CF3 + F2 → CF4 + ·F
Temperature:
269 - 356
K
Pressure: 1.07E-2 - 0.13 bar
Rate expression:
2.51x10-11 [±1.66x10-11 cm3/molecule s] e-8813 [±8314472 J/mole]/RT
Bath gas:
(CF3)2CO
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 269 | 4.87E-13 |
| 275 | 5.31E-13 |
| 300 | 7.32E-13 |
| 325 | 9.61E-13 |
| 350 | 1.21E-12 |
| 356 | 1.28E-12 |