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Title: The photolysis of CF3I in the presence of O2 and Br2. 1. The mechanism of the elementary step in the reaction of CF3 radicals with O2
Journal: Bull. Acad. Sci. USSR Div. Chem. Sci. (Engl. Transl.)
Volume: 8
Page(s): 1534 - 1537
Year: 1978
Reference type: Journal article
Squib: 1978VED/TEI1534-1537
Reaction:
·CF3 + O2 → CF3O2
Reaction order:
2
Reference reaction:
·CF3 + Br2 → CF3Br + Br·
Temperature:
296
K
Pressure: 1.33E-3 - 0.92 bar
Rate expression:
1.5x10-12 [cm3/molecule s]
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
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