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Title: Theory of thermal unimolecular reactions at high pressures. II. Analysis of experimental results
Journal: J. Chem. Phys.
Volume: 83
Page(s): 1010 - 1015
Year: 1985
Reference type: Journal article
Squib: 1985COB/TRO1010-1015
Reaction:
·CF3 + O2 → CF3O2
Reaction order:
2
Temperature:
300 - 1500
K
Rate expression:
2.59x10-11 [cm3/molecule s] e-2611 [J/mole]/RT
Bath gas:
Products
Category: Theory
Data type:
Transition state theory
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 300 | 9.10E-12 |
| 400 | 1.18E-11 |
| 500 | 1.38E-11 |
| 600 | 1.53E-11 |
| 700 | 1.65E-11 |
| 800 | 1.75E-11 |
| 900 | 1.83E-11 |
| 1000 | 1.89E-11 |
| 1100 | 1.95E-11 |
| 1200 | 1.99E-11 |
| 1300 | 2.03E-11 |
| 1400 | 2.07E-11 |
| 1500 | 2.10E-11 |